Prussian Blue Pigment

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SKU
417-17

Discovered in 1704 or 1705, Prussian blue is generally regarded as the first of the modern colors. In truth it is something of an anomaly, appearing well before the blossoming of chemistry as a science in the late 18th century.

Prussian Blue like so many other innovations in color, was the result of a serendipitous accident. Prussian blue is a synthetic organic pigment of deep blue hue with greenish tint.

Pigment Names
Common Names: English: Prussian blue
French: bleu prussien, bleu de Prusse
German: Preussisch Blau
Italian: azzurro di Prussia
Japanese: konjō, berensu
Russian: берлинская лазаурь
Spanish: azul de Prussia
Synonyms: English: Berlin blue, iron blue, Milori blue, Paris blue, Turnsbull blue
German: Berlinerblau, Pariserblau, Turnbullsblau
Italian: azzurro di Berlin
Spanish: azul de Berlin
Nomenclature:
Common Name Primary Mineral Source
Prussian Blue (Milori Blue) None India

Origin and History

A Berlin-based color maker, Heinrich Diesbach, was working in the laboratory of the alchemist Johann Konrad Dippel, and in the course of preparing a red lake pigment, Diesbach asked Dippel for some potash (a potassium alkali).

Presumably to economize, Diesbach requested a batch of potash contaminated with oils prepared from animal blood. It was a false economy, for his pigment turned out very pale. Attempting to concentrate it, he succeeded instead in turning it deep blue. He had no idea what had transpired, but was astute enough to recognize the blue material as a potential pigment in its own right, and was soon manufacturing it according to a jealously guarded recipe.

Iron blue was first mentioned in 1710 in a Latin text written by an unknown author and its properties were described in a reference from 1726. It is said to have been discovered by the chemist and painter Diesbach in 1704, but other sources mention the chemist Johann Conrad Dippel, for whom Diesbach worked.

The first mention of its manufacture was by the English chemist John Woodward in 1726. Potash and ox blood were heated until they glowed and then subsequently boiled with rainwater. The "blood lye" obtained in this way was heated together with a sulfate and alum. This produced a green intermediate product, also called "mountain green" or "crysocollage green." The material was then washed and filtered. After a treatment with hydrochloric acid, the product eventually turned to a deep blue color. It was particularly valued for mixing light blues, and appears in skies by Watteau, Canaletto and Gainsborough.

Source

Our Prussian blue is made according to the process originated by the French colormarker, Milori & Company, Lyons, France, known as the Milori process.

Permanence and Compatibility

Prussian blue is stable in weak acids, but is decomposed by weak alkalis, so it is suitable for oil, encaustic (non-emulsified or saponified type), egg tempera and watercolor, but not fresco and casein.

Oil Absorption and Grinding

Prussian blue absorbs a moderately high amount of oil (40–50 grams of linseed oil per 100 grams of pigment) to make a paste.

Toxicity

Prussian blue is not considered toxic, however, care should be used in handling the dry powder pigment to avoid inhaling the dust.

For more information on how to handle pigments safely, please visit How to Safely Handle Art Materials and Pigments.

Pigment Information
Color: Blue
Pigment Classification: Synthetic inorganic
Colour Index: Pigment Blue 27 (77510:1)
Chemical Name: Iron(II,III) Hexacyanoferrate(II,III)
Chemical Formula: Fe(NH4) [Fe (CN)6]•xH2O
CAS No.: 14038-43-8
Series No.: 3
ASTM Lightfastness
Acrylic: I
Oil: I
Watercolor: I
Physical Properties
Particle Size (mean): 0.4 micron
Density: 1.80 g/cm3
Hardness:
Refractive Index: 1.56–1.662
Oil Absorption: 40–50 grams oil / 100 grams pigment
pH (10% Aqueous Slurry):  3.0–5.0
Heat Stability: 177° C (350° F)
Munsell Value: 4.54PB 2.43/6.16
Health and Safety There are no acute or known chronic health hazards associated with the anticipated use of this product (most chemicals are not fully tested for chronic toxicity). Always protect yourself against potentially unknown chronic hazards of this and other chemical products by keeping them out of your body. Do this by avoiding ingestion, excessive skin contact, and inhalation of spraying mists, sanding dusts and vapors from heating. Conforms to ASTM D-4236.

For a detailed explanation of the terms in the table above, please visit Composition and Permanence.

More Information
SKU417-17
BrandRublev Colours
VendorRublev Colours
Processing TimeUsually ships the next business day.
ColorBlue
Pigment TypeInorganic, Synthetic

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